Selective synthesis of 12-molybdophosphoric acid.
نویسندگان
چکیده
منابع مشابه
Synthesis, Characterization and Catalytic Performance of a Novel Picolinic Acid‐12‐Molybdophosphoric Acid Hybrid Catalyst
A novel 12-molybdophosphoric acid (HPM)-based complex (H2PI)2(H3O)[PMo12O40] [Mo2O5(H2O)2(PI)2]·11H2O (PI-HPM) was prepared by modification with picolinic acid (HPI) and characterized by the methods of Fourier transform infrared (FTIR) spectroscopy, thermogravimetry (TG), X-ray powder and single crystal diffraction. The complex retained the classical Keggin structure of bulk HPM, there were som...
متن کاملSize-controlled and Green Synthesis of Metal Nanoparticles Using Molybdophosphoric Acid
Green synthesis of silver and gold nanoparticles as two metal nanoparticles, was studied based on photoreduction of metal ions using molybdophosphoric acid (H3[PMo12O40], HPMo) under UV-irradiation. HPMo was found to be photocatalyst, reducing agent and efficient stabilizer for the resulting nanoparticles. This method allows the size-controlled synthesis of uniform nanoparticles with an average...
متن کاملGreen procedure for synthesis of 3, 4 dihydropyrimidinones using 12-molybdophosphoric acid, as a catalyst and solvent free condition under microwave irradiation
Simple and improved conditions have been found to carry out the Biginelli reaction for the synthesis of 3, 4-dihydropyrimidin-2(1H) - one derivatives. This synthesis was performed in the presence of 12-molybdophosphoric acid (H3PMo12O40) as catalyst. These reactions were performed under solvent free conditions with microwave irradiation as the energy source. Compared with the classical Biginell...
متن کاملApplication of Molybdophosphoric Acid as Reducing Agent/ Stabilizer in the Synthesis of Gold Nanoparticles under UV Irradiation
In this paper, we have described the size-controlled synthesis of gold nanoparticles based on the reduction of Au3+ (HAuCl4 ) using molybdophosphoric acid (H3[PMo12O40 ], HPMo) under UV-irradiation. In the process, HPMo plays the role of photocatalyst, reducing agent and stabilizer and propan-2-ol acts as a sacrificial agent. This method allows the synthesis of uniform hexagonal nanoparticles w...
متن کاملapplication of molybdophosphoric acid as reducing agent/ stabilizer in the synthesis of gold nanoparticles under uv irradiation
in this paper, we have described the size-controlled synthesis of gold nanoparticles based on the reduction of au3+ (haucl4 ) using molybdophosphoric acid (h3[pmo12o40 ], hpmo) under uv-irradiation. in the process, hpmo plays the role of photocatalyst, reducing agent and stabilizer and propan-2-ol acts as a sacrificial agent. this method allows the synthesis of uniform hexagonal nanoparticles w...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: NIPPON KAGAKU KAISHI
سال: 1987
ISSN: 2185-0925,0369-4577
DOI: 10.1246/nikkashi.1987.969